山東埃爾派 | 點擊量:0次 | 2020-04-06
高嶺土在多孔陶瓷中的應用 埃爾派豐富高嶺土生產工藝流程
粘(zhan)(zhan)性是指流體內部(bu)由于內摩(mo)擦作用(yong)而阻礙其(qi)相對流動的(de)一種特征,以粘(zhan)(zhan)度來(lai)表示其(qi)大(da)小(作用(yong)于1單位(wei)面積的(de)內摩(mo)擦力),單位(wei)是Pa·s。粘(zhan)(zhan)度的(de)測定(ding),一般(ban)采用(yong)旋轉粘(zhan)(zhan)度計,以在含70%固含量的(de)高(gao)嶺(ling)土泥(ni)漿(jiang)中的(de)轉速(su)來(lai)衡量。在生產工藝中,粘(zhan)(zhan)度具有重要意義,它不僅是陶瓷工業的(de)重要參數(shu),對造紙(zhi)工業影響也(ye)很大(da)。據資料表明(ming),國(guo)外用(yong)高(gao)嶺(ling)土作涂料,在低速(su)涂布時(shi)要求粘(zhan)(zhan)度約0.5Pa·s,高(gao)速(su)涂布時(shi)要求小于1.5Pa·s。
多(duo)孔(kong)(kong)(kong)(kong)(kong)(kong)材(cai)(cai)料(liao)是指具(ju)有一(yi)(yi)定尺寸和數量(liang)(liang)的孔(kong)(kong)(kong)(kong)(kong)(kong)隙結(jie)構(gou)的材(cai)(cai)料(liao),通常孔(kong)(kong)(kong)(kong)(kong)(kong)隙度(du)較(jiao)(jiao)大,孔(kong)(kong)(kong)(kong)(kong)(kong)隙結(jie)構(gou)作(zuo)為(wei)(wei)(wei)有用的結(jie)構(gou)存在(zai)。而(er)多(duo)孔(kong)(kong)(kong)(kong)(kong)(kong)陶(tao)(tao)(tao)瓷(ci)(ci)(ci)(porousceramics)是一(yi)(yi)種新型陶(tao)(tao)(tao)瓷(ci)(ci)(ci)材(cai)(cai)料(liao),也稱氣孔(kong)(kong)(kong)(kong)(kong)(kong)功(gong)能(neng)陶(tao)(tao)(tao)瓷(ci)(ci)(ci),它是成(cheng)型后經高溫燒成(cheng),體內具(ju)有大量(liang)(liang)彼此(ci)相通或閉合氣孔(kong)(kong)(kong)(kong)(kong)(kong)的陶(tao)(tao)(tao)瓷(ci)(ci)(ci)材(cai)(cai)料(liao)。多(duo)孔(kong)(kong)(kong)(kong)(kong)(kong)陶(tao)(tao)(tao)瓷(ci)(ci)(ci)種類(lei)(lei)繁多(duo),一(yi)(yi)般根(gen)據孔(kong)(kong)(kong)(kong)(kong)(kong)徑大小分(fen)為(wei)(wei)(wei)三(san)類(lei)(lei):孔(kong)(kong)(kong)(kong)(kong)(kong)徑小于2nm的稱為(wei)(wei)(wei)微孔(kong)(kong)(kong)(kong)(kong)(kong)陶(tao)(tao)(tao)瓷(ci)(ci)(ci),孔(kong)(kong)(kong)(kong)(kong)(kong)徑介(jie)于2〜50nm之間的稱為(wei)(wei)(wei)介(jie)孔(kong)(kong)(kong)(kong)(kong)(kong)陶(tao)(tao)(tao)瓷(ci)(ci)(ci),孔(kong)(kong)(kong)(kong)(kong)(kong)徑大于50nm的稱為(wei)(wei)(wei)宏(hong)孔(kong)(kong)(kong)(kong)(kong)(kong)陶(tao)(tao)(tao)瓷(ci)(ci)(ci);根(gen)據成(cheng)孔(kong)(kong)(kong)(kong)(kong)(kong)方法(fa)和孔(kong)(kong)(kong)(kong)(kong)(kong)隙結(jie)構(gou)的不同,多(duo)孔(kong)(kong)(kong)(kong)(kong)(kong)陶(tao)(tao)(tao)瓷(ci)(ci)(ci)可分(fen)為(wei)(wei)(wei)三(san)類(lei)(lei):粒狀陶(tao)(tao)(tao)瓷(ci)(ci)(ci)燒結(jie)體、泡沫陶(tao)(tao)(tao)瓷(ci)(ci)(ci)和蜂窩陶(tao)(tao)(tao)瓷(ci)(ci)(ci)。多(duo)孔(kong)(kong)(kong)(kong)(kong)(kong)陶(tao)(tao)(tao)瓷(ci)(ci)(ci)因其具(ju)有良(liang)好的化學穩定性和耐熱性、較(jiao)(jiao)高的剛度(du)及機(ji)械強度(du),可作(zuo)為(wei)(wei)(wei)過濾(lv)、分(fen)離、吸聲(sheng)、隔(ge)膜(mo)、生(sheng)物陶(tao)(tao)(tao)瓷(ci)(ci)(ci)、敏感材(cai)(cai)料(liao)和催化劑載體而(er)被廣泛應(ying)用于石油、化工、環保、冶金(jin)、機(ji)械、生(sheng)物和醫藥等行(xing)業(ye)。
高嶺(ling)土是陶瓷(ci)工(gong)業(ye)的重要原(yuan)料(liao)。He等利(li)用高嶺(ling)土加工(gong)設備(bei),高嶺(ling)土加工(gong)技(ji)術(shu)、炭(tan)(tan)作為原(yuan)材料(liao)通過原(yuan)位(wei)反(fan)(fan)應(ying)及熱(re)(re)壓燒(shao)結制(zhi)備(bei)Al2O3/SiC復(fu)相(xiang)(xiang)陶瓷(ci)材料(liao)。研(yan)究表(biao)明,理(li)想的粉(fen)末(mo)合成(cheng)溫度(du)為1550℃,Al2O3/SiC復(fu)相(xiang)(xiang)陶瓷(ci)粉(fen)末(mo)通過熱(re)(re)壓燒(shao)結合成(cheng)復(fu)相(xiang)(xiang)陶瓷(ci),抗彎強度(du)達到(dao)420MPa,相(xiang)(xiang)對密(mi)度(du)達到(dao)0.98,硬度(du)為89HRA。鄒(zou)正(zheng)光等利(li)用原(yuan)位(wei)炭(tan)(tan)熱(re)(re)還原(yuan)法,以天然高嶺(ling)土和(he)炭(tan)(tan)黑為原(yuan)料(liao),實現(xian)了Al2O3/SiC復(fu)相(xiang)(xiang)陶瓷(ci)粉(fen)末(mo)的合成(cheng)和(he)制(zhi)備(bei),探討了Al2O3/SiC復(fu)相(xiang)(xiang)陶瓷(ci)材料(liao)的反(fan)(fan)應(ying)形(xing)(xing)成(cheng)機(ji)(ji)理(li)。根(gen)據熱(re)(re)力學分析,認為Al2O3/SiC復(fu)相(xiang)(xiang)陶瓷(ci)粉(fen)末(mo)的合成(cheng)反(fan)(fan)應(ying)形(xing)(xing)成(cheng)機(ji)(ji)理(li)是:首先(xian),高嶺(ling)土脫水并轉變成(cheng)莫(mo)(mo)來石;然后在(zai)轉變中產(chan)生(sheng)(sheng)的SiO2和(he)C發(fa)生(sheng)(sheng)反(fan)(fan)應(ying)生(sheng)(sheng)成(cheng)SiC,及C和(he)莫(mo)(mo)來石發(fa)生(sheng)(sheng)反(fan)(fan)應(ying)產(chan)生(sheng)(sheng)Al2O3和(he)SiC,得到(dao)Al2O3/SiC不同含量的復(fu)相(xiang)(xiang)陶瓷(ci)粉(fen)末(mo)。合成(cheng)適宜(yi)溫度(du)是1550℃。
埃爾派超(chao)微(wei)(wei)粉碎(sui)機:種(zhong)類各(ge)異,規格齊全。各(ge)種(zhong)超(chao)硬(ying)、超(chao)純(chun)、韌性、粘性、易燃(ran)、易爆物料,都能找到最(zui)適(shi)合的(de)機型。最(zui)新設(she)計推出的(de)D97<2微(wei)(wei)米的(de)超(chao)微(wei)(wei)粉碎(sui)機,已達到歐美先進水平(ping)。
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